Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex.
نویسندگان
چکیده
The activation of CO2, CS2 as well as of PhNCO at [Rh(Bpin)(PEt3)3] led to C=X bond cleavage and the formation of {RhXBpin} species (X = O, S, N). Treatment of the boryl complex [Rh(Bpin)(PEt3)3] with 0.5 equivalents of CS2 resulted in the fragmentation of CS2 and the formation of the remarkable μ-carbido complex trans-[Rh2(μ-C)(SBpin)2(PEt3)4].
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 78 شماره
صفحات -
تاریخ انتشار 2015